NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether

NCERT Solutions for Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether is designed and prepared by the best teachers across India. All the important topics are covered in the exercises and each answer comes with a detailed explanation to help students understand concepts better. These NCERT solutions play a crucial role in your preparation for all exams conducted by the CBSE, including the JEE.

NCERT SOLUTIONS CLASS 12TH CHEMISTRY

Topics and Subtopics in NCERT Solutions for Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether:

Section NameTopic Name
11Alcohols, Phenols and Ethers
11.1Classification
11.2Nomenclature
11.3Structures of Functional Groups
11.4Alcohols and Phenols
11.5Some Commercially Important Alcohols
11.6Ethers

NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether

NCERT Solutions CBSE Sample Papers ChemistryClass 12 Chemistry

NCERT TEXTBOOK QUESTIONS SOLVED

11.1. Classify the following as primary, secondary, and tertiary alcohols.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q1

NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q1.1

NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q1.2
Ans: Primary alcohols: (i), (ii), (iii)
Secondary alcohols: (iv), (v)
Tertiary alcohols: (vi)

11.2. Identify aliylic alcohols in the above examples.
Ans: (ii) and (iv) i.e. H2C=CH – CH2OH and
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q2

11.3. Name the following compounds according to IUPAC system.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q3
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q3.1

NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q3.2

11.4. Show how are the following alcohols prepared by the reaction of a suitable  Grignard reagent on methanal ?
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q4
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q4.1

NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q4.2

11.5. Write structures of the products of the following reactions:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q5
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q5.1

11.6. Give structures of the products you would expect when each of the following alcohol reacts with (a)HCl-ZnCl2 (b)HBrand (c) SOCl2
(i)Butan-1-ol
(ii)2-Methylbutan-2-ol
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q6

NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q6.1

11.7. Predict the major product of acid catalysed dehydration of
(i) 1-nicthylcyclohcxanoland
(ii) butan-1-ol
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q7

11.8. Ortho and para nitrophenols are more acidic than phenol. Draw the resonance structures of the corresponding phenoxide ions.
Ans:
The resonance structures of o-and p- nitrophenoxide ions and phenoxide ion are given below:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q8

NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q8.1

11.9; Write the equations involved in the following reactions:
(i) Reimer-Tiemann reaction
(ii) Kolbe’s reaction
Ans: (i) Reimer-Tiemann reaction
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q9

11.10. Write the reactions of Williamson synthesis of 2-ethoxy-3-methylpentane starting from ethanol and 3-methylpentan-2-ol.
Ans: In Williamsons’s synthesis, the alkyl halide should be primary. Thus, the alkyl halide should be derived from ethanol and the alkoxide ion from 3-methylpentan-2-ol. The synthesis is as follows
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q10

NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q10.1

11.11. Which of the following is an appropriate set of reactants for the preparation of l-methoxy-4- nitrobenzene and why?
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q11
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q11.1

11.12. Predict the products of the following reactions:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q12
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Intext Questions Q12.1

NCERT EXERCISES

11.1. Write IUPAC names of the following compounds:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q1

NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q1.1

NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q1.2
Ans: (i) 2,2,4-Trimethylpentan-3-ol
(ii) 5-Ethylheptane-2,4-dioI
(iii) Butane-2,3-diol
(iv) Propane-1,2,3-triol
(v) 2-Methylphenol
(vi) 4-Methylphenol
(vii) 2,5-DimethylphenoI
(viii) 2,6-Dimethylphenol
(ix) 1-Methoxy-2-methylpropane
(x) Ethoxybenzene
(xi) 1-Phenoxyheptane
(xii) 2-Ethoxybutane

11.2. Write structures of the compounds whose IUPAC names are as follows:
(i)2-Methylbutan-2-ol
(ii)l-Phcnylpropan-2-ol
(iii)3,5-DimethyIhexane-l,3,5-triol
(iv)2,3-Dicthylphenol
(v)1-Ethoxypropane
(vi)2-Ethoxy-3-methylpentane
(vii) Cyclohexylmethanol
(viii) 3-Cyclohexylpcntan-3-ol
(ix)Cyclopcnt-3-en-l-ol
(x)4-ChIoro-3-ethylbutan-l-ol
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q2

NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q2.1

11. 3. (a) Draw the structural formulas and write IUPAC names of all the isomeric alkanols with the molecular formula CsH12O
(b) Classify the isomers of alcohols given in part (a) as primary, secondary and tertiary alcohols.
Ans:
(a) The molecular formula C5H120 represents eight isomeric alkanols. These are :
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q3

(b) Praimary: (i), (ii), (iii), (iv) ; Secondary :(v), (vi), (viii) ; Tertiary : (vii)

11.4. Explain why propanol has higher boiling point than that of the hydrocarbon, butane?
Ans: The molecules of butane are held together by weak van der Waal’s forces of attraction while those of propanol are held together by stronger intermolecular hydrogen bonding.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q4

11.5. Alcohols are comparatively more soluble in water than hydrocarbons of comparable molecular masses. Explain this fact.
Ans: Alcohols can form hydrogen bonds with water and by breaking the hydrogen bonds already existing between water molecules. Therefore, they are soluble in water.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q5
On die other hand, hydrocarbons cannot from hydrogen bonds with water and hence are insoluble in water.

11.6. What is meant by hydroboration-oxidation reaction? Illustrate it with an example.
Ans: The addition of diborane to alkenes to form trialkyl boranes followed by their oxidation with alkaline hydrogen peroxide to form alcohols is called hydroboration-oxidation. For example,
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q6

11.7. Give the structures and IUPAC names of monohydric phenols of molecular formula, C7H8O.
Ans: The three isomers are:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q7

11.8. While separating a mixture of ortho and para nitrophenols by steam distillation, name the isomer which will be steam volatile. Give reason.
Ans: 0-N itrophenol is steam volatile due to chelation (intramolecular H – bonding) and hence can be separated by steam distillation from/Miitrophenol which is hot steam volatile because of intermolecular H-bonding.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q8

11.9. Give the equations of the reaction for the preparation of phenol from cumene.
Ans: This process has a great industrial importance because it gives the preparation of two very useful compounds i.e. phenol and acetone. The raw materials are benzene and propene and it initially proceeds by Friedel Crafts alkylation of benzene.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q9
Oxygen is bubbled through the above solution to form cumene hydroperoxide which is decomposed with aqueous acid
solution to form phenol and acetone as follows:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q9.1

11.10. Write chemical reaction for the preparation of phenol from chlorobenzene.
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q10

11.11. Write the mechanism of hydration of ethene to yield ethanol.
Ans: Direct addition of H20 to ethene in presence of an acid does not occur. Indirectly, ethene is first passed through concentrated H2S04, when ethyl hydrogen sulphate is formed.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q11

11.12. You are given benzene, cone. H2S04and NaOH. Write the equations for the preparation of phenol using these reagents.
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q12

11.13. Show how will you synthesise
(i) 1 -phenylethanol from a suitable alkene.
(ii) cyclohexylmethanol using an alkyl halide by an SN2 reaction.
(iii) Pentan-l-ol using a suitable alkyl halide?
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q13

11.14. Give two reactions that show the acidic nature of phenol. Compare its acidity with that of ethanol.
Ans: The reactions showing acidic nature of phenol are:
(a) Reaction with sodium: Phenol reacts with active metals like sodium to liberate H, gas.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q14
(b) Reaction with NaOH: Phenol dissolves in NaOH to form sodium phenoxide and water.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q14.1
Phenol is more acidic than ethanol. This is due to the reason that phenoxide ion left after the loss of a proton from phenol is stabilized by resonance, while ethoxide ion left after less of a proton from ethanol, is not.

11.15. Explain why is orthonitrophenol more acidic than orthomethoxyphenol?
Ans: Nitro (NO2) group is an electron withdrawing group while methoxy (OCH3) group is electron releasing in nature. The release of H+ ion is therefore, easier from o-nitrophenol while it is quite difficult from o-methoxyphenol. Apart form that, o-nitrophenoxide ion is stabilised due to resonance o-nitrophenol is steam volatile while p-nitrophenol is not. This is on account of intramolecular hydrogen bonding in the molecules of o-nitrophenol. As a result, its boiling point is less than that of p-nitrophenol in which the molecules are linked by intermolecular hydrogen bonding.
It is interesting to note that in the substituted phenols, the nature and position of the substituent influences the boiling point of phenol.
For example: .o-nitrophenol is steam volatile while p-nitrophenol is not. This is supported by the fact that the boiling point temperature of o-nitrophenol (100°C) is less than that of p-nitrophenol, (279°C). In o-nitrophenol, there is intramolecular hydrogen bonding in OH and NO2 groups placed in a adjacent positions. However, these are linked by intermolecular hydrogen bonding in the p-isomers. It is quite obvious that extra energy is needed to the cleave the hydrogen bonds in the p-isomer. Consequently, its boiling point is more.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q15
o-nnrophenol with lower boiling point is steam volatile while p-nitrophenol is not. This helps in the separation of the two isomers present in the liquid mixture.  On passing steam, o-nitropbenol volatilises and its vapours rise alongwith steam and after condensation, collect in the receiver p-nitrophenol is left behind in the distillation flask. e-nkrophenol p-nnrophenol.
On the contrary, o-methoxyphenoxide is destabilised since the electron density on the negatively charged oxygen tends to increase due to the electron releasing tendency of the methoxy(OCH3) group.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q15.1
In the light of the above discussion, we may conclude that o-nitrophenol is a stronger acid (pKa = 7-23) than o-methoxyphenl  (pKa = 9.98)

11.16. Explain how does the – OH group attached to a carbon of benzene ring activate it towards electrophilic substitution?
Ans: Phenol may be regarded as a resonance hybrid of structures I-V, shown below.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q16
As a result of +R effect of the -OH group, the electron density in the benzene ring increases thereby facilitating the attack of an electrophile. In other words, presence of -OH group, activates the benzene ring towards electrophilic substitution reactions. Further, since the electron density is relatively higher at the two o-and one p-position, therefore electrophilic substitution occurs mainly at o-and p-positions.

11.17. Give equations of the following reactions:
(i) Oxidation of propan-l-ol with alkaline KMnO4 solution.
(ii) Bromine in CS2 with phenol.
(iii) Dilute HNO3 acid with phenol
(iv) Treating phenol with chloroform in presence of aqueous NaOH.
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q17

11.18. Explain the following with an example
(i) Kolbe’s reaction
(ii) Reimer – Tiemann reaction –

(iii) Williamson ether synthesis
(iv) Unsymmetrical ether

Ans: (i) Kolbe’s reaction: Sodium phenoxide when heated with C02 at 400K under a pressure of 4-7 atmospheres followed by acidification gives 2-hydroxybenzoic acid (salicylic acid) as the major product along with a small amount of 4-hydroxybenzoic acid.This reaction is called Kolbe’s reaction.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q18
(ii) Reimer-Tiemann reaction: Treatment of phenol with CHC13 in presence of aqueous sodium or potassium hydroxide at 340 K followed by hydrolysis of the resulting product gives 2-hydroxybenzaldehyde (salicyialdehyde) as the major product. This reaction is called Reimer-Tiemann reaction.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q18.1
(iii) Williamson’s ether synthesis: It involves the treatment of an alkyl halide with a suitable sodium alkoxide to obtain ethers. The sodium alkoxide needed for the purpose is prepared by the action of sodium on a suitable alcohol. In this reaction alkyl halide should primary. Secondary and tertiary halides will predominantly give an alkene.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q18.2
(iv) Unsymmetrical ether: If the alkyl or aryl groups attached to the oxygen atom are different, ethers are called unsymmetrical ethers. For example, ethyl methyl ether, methyl phenyl ether, 4-chlorophenyl- 4-nitrophenyl ether, etc.

11.19. Write the mechanism of acid dehydration of ethanol to yield ethene.
Ans: The mechanism of dehydration of alcohols to form alkenes occur by the following three steps:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q19

11.20. How are the following conversions carried out?
(i) Propane → Propan-2-ol
(ii) Benzyl chloride → Benzyl alcohol
(iii) Ethyl mag. chloride → Propan-1-ol
(iv) Methyl mag. bromide → 2-Methylpropan-2-ol.
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q20

11.21. Name the reagents used in the following reactions:
(i) Oxidation of a primary alcohol to carboxylic acid.
(ii) Oxidation of a primary alcohol to aldehyde.
(iii) Brominationofphenolto2,4,6-tribromophenol
(iv) Benzyl alcohol to benzoic acid.
(v) Dehydration of propan-2-oI to propene.
(vi) Butan-2-one to butan-2-oL .
Ans: (i) Acidified potassium dichromate or neutral/ acidic/ alkaline potassium permanganate.
(ii) Pyridinium chlorochromate (PCC), (C5H5NH)+ ClCrO3– in CH2Cl2
or Pyridinium dichromate (PDC),[(C5H5NH)2]2+Cr2O72-in CH2Cl2
(iii) Aqueous bromine, i.e., Br2/H2O.
(iv) Acidified or alkaline potassium permanganate.
(v) 85% H2S04 at 440 K.
(vi) Ni/H2 or NaBH4 or LiAlH4.

11.22. Give reason for the higher boiling point of ethanol in comparison to methoxymethane.
Ans: Ethanol undergoes intermolecular H-bonding due to the presence of a hydrogen atom attached to the electronegative oxygen atom. As a result, ethanol exists as associated molecules.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q22
Consequently, a large amount of energy is required to break these hydrogen bonds. Therefore, the boiling point of ethanol is higher than that of methoxymethane which does not form H-bonds.

11.23. Give IUPAC names of the following ethers.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q23
Ans: (i)1-Ethoxy-2-methylpropane
(ii) 2-Chlorlo-l-methoxy ethane
(iii) 4-Nitroanisole
(iv) 1-Methoxypropane
(v) 1 -Ethoxy-4 -4 – dimethyl cyclohexane
(vi)Ethoxybenzene

11,24. Write the names of the reagents and equations for the preparation of the following ethers by Williamson’s synthesis :
(i) 1-Propoxypropane
(ii) 2-Methoxy-2-methylpropane
(iii) Ethoxybenzene
(iv) Methoxyethane.
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q24

11.25. Illustrate with examples the limitations of Willamson synthesis for the preparation of certain types of ethers. 
Ans: Williamson’s synthesis is a versatile method for the synthesis of both symmetrical and unsymmetrical ethers. However, for the synthesis of unsymmetrical ethers, a proper choice of reactants is necessary. Since Williamson’s synthesis occurs by SN2 mechanism and primary alkyl halides are most reactive in Sn2 reaction, therefore, best yields of unsymmetrical ethers are obtained when the alkyl halides are primary and the alkoxide may be primary, secondary or tertiary. For example, tert-butylethyl ether is prepared by treating ethyl bromide with sodium tert-butoxide.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q25

11.26. How is 1-propoxypropane synthesised from propane-1-ol? Write mechanism of the reaction. (C.B.S.E. Sarnie Paper 2015)
Ans: Two methods can be used for the synthesis of 1-propoxypropane from propan-1-ol
By Williamson’s synthesis
The halogen derivative such as bromoderivative and sodium salt of the alcohol take part in the Williamson’s synthesis
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q26

NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q26.1

11.27. Preparation of ethers by acid dehydration of secondary or tertiary alcohols is not a suitable method. Give reason.
Ans: Acid catalysed dehydration of primary alcohols to ethers occurs by SN2 reaction involving nucleophilic attack by the alcohol molecule on the protonated alcohol molecule.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q27
Under these conditions, 2° and 3° alcohols, however, give alkenes rather than ethers. The reason being that due to steric hindrance, nucleophilic attack by the alcohol molecule on the protonated alcohol molecule does not occur. Instead protonated 2° and 3° alcohols lose a molecule of water to form stable 2° and 3° carbocation. These carbocations prefer to lose a proton to form alkenes rather than undergoing nucleophilic attack by alcohol molecules to form ethers.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q27.1

11.28. Write the equation of the reaction of hydrogen iodide with (i)1-propoxypropane (ii)methoxybenzene, and (iii)benzyl ethyl ether
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q28

NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q28.1

11.29. Explain the fact that in alkyl aryl ethers, alkoxy group :
(i) activates the benzene ring towards electrophilic substitution.
(ii) directs the incoming substituents towards ortho and para positions in the ring.
Ans:
(i) The alkoxy group (RO -) with lone electron pairs on the oxygen atom activates the ortho and para positions in the ring by + M (or + R) effect as shown below :
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q29
As the ortho and para positions in the ring become points of high electron density, the electrophiles prefer to attack these positions.

(ii) The alkoxy group directs the incoming group which is an electrophile towards the ortho and para positions in the ring. As a result, a mixture of isomeric products is formed.

11.30. Write the mechanism of the reaction of HI with methoxymethane.
Ans: When equimolar amounts of HI and methoxy methane are reacted, a mixture of methyl alcohol and methyl iodide is formed by the following mechanism:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q30

11.31. Write equations of the following reactions:
(i) Friedel-Crafts reaction -alkylation of anisole
(ii) Nitration of anisole.
(iii) Bromination of anisole in ethanoic acid medium
(iv) Friedel-Craft’s acetylation of anisole.
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q31

NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q31.1

11.32. Show how will you synthesise the following from appropriate alkenes.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q32
Ans: All the alcohols are formed by the hydration of alkenes in the acidic medium. The addition follows Markownikov’s rule. 1-Methylcyclohexene can be used in the reaction.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q32.1
(ii)  4-Methylpent-3-ene upon hydration in the acidic medium will give the desired alcohol.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q32.2
(iii) Pent-2-ene gives the desired alcohol upon hydration in the presence of acid.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q32.3
(iv) The cyclic alkene used in this reaction is 2-cyclohexylbut-2-ene.
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q32.4

11.33. When 3-methylbutant 2-ol is treated with HBr, the following reaction takes place:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q33
Give a mechanism for this reaction.
(Hint: The secondary carbocation formed in step II rearranges to a more stable tertiary carbocation by a hydride ion shift from 3rd carbon atom.)
Ans:
NCERT Solutions For Class 12 Chemistry Chapter 11 Alcohols Phenols and Ether Exercises Q33.1
Protonation of the given alcohol followed by loss of water gives a 2° carbocation(I), which being unstable rearranges by 1,2-hydride shift to form the more stable 3° carbocation (II). Nucleophilic attack by Br ion on this carbocation (II) gives the final product.

Download the PDF of NCERT Solutions from Here

Class 12 Chemistry NCERT Solutions

More Resources for NCERT Solutions Class 12:

Leave a Comment

This site uses Akismet to reduce spam. Learn how your comment data is processed.